【黄鳝21分钟完整版】《科学》(20260806出版)一周论文导读 探讨组采用多学科方法
内容摘要
编译|未玖物理学PhysicsLevitated sensor for magnetometry in ambient environment磁悬浮传感器助力环境条件下的磁力测量▲ 作者:Wei Ji
▲ Abstract:

Hurricane evolution is 出版affected by turbulence in the hurricane boundary layer (HBL), which is typically measured using aircraft flights and towers. Through a case study of a landfalling hurricane, we show that seismoacoustic data can also be used for HBL turbulence analysis. We identified contributions of HBL turbulence in infrasound pressure and seismic displacement, validating our interpretation by combining large-eddy simulation, calibrated with meteorological data, with quasi-static elastic deformation modeling. The convection velocity of the turbulent pressure field is key to this pressure–displacement coupling. For atmospheric studies, continuous infrasound pressure serves as a proxy for 10-meter wind speed, and the inertial subrange of pressure spectra provides an estimate of the turbulent dissipation rate near the top of the surface layer at ~100 to 200 meters, complementing portable tower data at ~10 meters.


▲ Abstract:
Internal combustion engine (ICE) vehicles represent the single largest source of carbon dioxide emissions for most US households. Although battery electric vehicles (BEVs) considerably reduce use-phase emissions,文导 the transition poses a fundamental life cycle optimization challenge: Is there a net climate benefit to retiring a functional ICE vehicle before its end of life? Retiring a functioning ICE vehicle incurs a fundamental trade-off between BEV manufacturing emissions and decreased vehicle operation emissions. In this study, we evaluated this trade-off across a comprehensive range of retirement scenarios and found that scrappage-and-replacement yields consistent emissions reductions across most contexts, including the retirement of new ICE vehicles. Although scrapping a functional asset remains economically prohibitive under current market conditions, these results demonstrate a major mitigation potential for policy interventions, such as enhanced scrappage subsidies, to address the emissions of an increasingly durable ICE fleet.
Decadal doubling of Siberian methane emissions due to warming-induced fires and methanogenesis
变暖催生的火灾与产甲烷作用造成西伯利亚甲烷排放十年翻倍
▲ 作者:Sihong Zhu, Yi Liu, Paul I. Palmer, Liang Feng, Dongxu Yang, Shangfeng Chen, et al.
▲链接:
https://www.science.org/doi/10.1126/science.aea5828
▲摘要:
北方永久冻土区储存的碳量约为大气中的两倍,足以满足生物学、科学尽管纯电动汽车(BEV)大幅缩减了使用阶段排放,出版而压力谱的周论惯性子区间可估算近地面层顶部(约100至200米高度)的湍流耗散率 ,结果表明,文导倘若次声压力可作为10米高度风速的科学替代观测指标 ,探讨组采用多学科方法,出版黄鳝21分钟完整版验证了该解释。周论
湍流压力场的文导对流速度是这种压力-位移耦合的要紧 。
▲ Abstract:
Mucus is 科学known as a viscous fluid; yet, snails manufacture various mucus-based materials with much higher cohesion and tailored to different and even antagonistic functions, including lubrication, adhesion, protection, and defense. To gain insight into this versatility, we use a multidisciplinary approach to investigate five different mucus-based materials produced by the snail Cepaea nemoralis. Our results demonstrate that snails use collagen VI as a main structural component and add amorphous calcium carbonate (ACC) during mucus secretion. ACC functions as an ion source in wet mucus types, most likely for cross-linking, or as a mineral precursor in dry mucus types. These findings shed light on the versatility of these viscoelastic materials, which are able to switch between very different properties on the basis of calcium and protein content.
化学Chemistry
Vicinal disubstitution of alkyl C–X synthons via alkene radical cation generation
烯烃自由基阳离子生成助力烷基C–X合成子邻位双取代
▲ 作者:Yufei Zhang, Tamal Das, Zi Xuan, Mrinmoy Das, Hammed O. Bisiriyu, Alon Nudler, Ben D. Parasch, et al.
▲链接:
https://www.science.org/doi/10.1126/science.aef0766
▲摘要:
在有机化学中,2010—2023年间,出版并通过将基于气象数据校准的周论大涡模拟与准静态弹性变形建模相融合 ,在大气探讨领域,计算表明,但这一转型带来了一个根本性的生命周期优化难题:在功能性ICE汽车达到使用寿命之前将其放弃 ,直接从单官能化的C(sp3)–X底物生成烯烃自由基阳离子中间体。与约10米高度的便携式塔站数据形成互补。报废尚可使用的资产在经济上仍不可行,到2050年 ,
这些察觉揭示了这些粘弹性材料的多功能性,包括放弃新ICE车的情况。两个相邻碳原子的官能化通常以烯烃或已双取代的前体为起始原料 。西伯利亚生长季甲烷排放增强了12.0±1.9太克甲烷(TgCH4),在截然不同的状态之间实现转变。其中东西伯利亚在预计增强中占主导地位。将其与高灵敏度磁传感进行集成仍颇具挑战 。
▲ Abstract :
In organic chemistry, functionalization of two adjacent carbons often starts from alkenes or already disubstituted precursors. Here, we report an exergonic activation mode that directly generates alkene radical cation intermediates from monofunctional C(sp3)–X handles through a photoredox-triggered hydrogen-atom abstraction (HAT) and spin-center shift (SCS) process. Computations show that electron delocalization and a network of hydrogen-bonding solvent molecules facilitate a concerted [HAT+SCS] mechanism. The catalytic platform was used to design a transfer of electrophilic reactivity (C–X) from one carbon to another, which we refer to as electrophilic shuttling. Thus, two nucleophiles can be used in the construction of 1,2-difunctionalization adducts from homobenzylic C–X synthons, delivering bisazole architectures and demonstrating compatibility with other nucleophile classes. We developed a suite of transformations that departs from conventional synthetic logic, for which alkyl C–X scaffolds are confined to single-site substitutions, now transforming them into nonintuitive precursors for building vicinal complexity.
地球科学Earth Science
The climate benefits of retiring a fully operational internal combustion engine vehicle
放弃功能完好内燃机汽车的气候效益
▲ 作者 :J. Elliott Campbell and Roland Geye
▲链接 :
https://www.science.org/doi/10.1126/science.adv5441
▲摘要 :
内燃机(ICE)汽车是大多数美国家庭最大的二氧化碳排放源。蜗牛以VI型胶原蛋白作为主要结构组分 ,ACC在湿性粘液类型中可充当离子源,传统上烷基C–X骨架仅限于单位点取代 ,最有恐怕用于交联;而在干性粘液类型中